منابع مشابه
Triazine-based carbon nitrides for visible-light-driven hydrogen evolution.
A new dimension: The doping of amorphous poly(triazine imide) (PTI) through ionothermal copolymerization of dicyandiamide with 4-amino-2,6-dihydroxypyrimidine (4AP) results in triazine-based carbon nitrides with increased photoactivity for water splitting compared to crystalline poly(triazine imide) (PTI/Li(+)Cl(-), see picture) and melon-type carbon nitrides. This family of carbon nitride semi...
متن کاملThe phase diagram and hardness of carbon nitrides
Novel superhard materials, especially those with superior thermal and chemical stability, are needed to replace diamond. Carbon nitrides (C-N), which are likely to possess these characteristics and have even been expected to be harder than diamond, are excellent candidates. Here we report three new superhard and thermodynamically stable carbon nitride phases. Based on a systematic evolutionary ...
متن کاملInterpretation of infrared and Raman spectra of amorphous carbon nitrides
A general framework for the interpretation of infrared and Raman spectra of amorphous carbon nitrides is presented. In the first part of this paper we examine the infrared spectra. The peaks around 1350 and 1550 cm found in the infrared spectrum of amorphous carbon nitride or hydrogenated and hydrogen-free amorphous carbon are shown to originate from the large dynamic charge of the more delocal...
متن کاملHard superconducting nitrides.
Detailed study of the equation of state, elasticity, and hardness of selected superconducting transition-metal nitrides reveals interesting correlations among their physical properties. Both the bulk modulus and Vickers hardness are found to decrease with increasing zero-pressure volume in NbN, HfN, and ZrN. The computed elastic constants from first principles satisfy c11 > c12 > c44 for NbN, b...
متن کاملResonant Raman spectra of amorphous carbon nitrides: the G peak dispersion
A general model is presented for the interpretation of the Raman spectra of amorphous carbon nitrides measured at any excitation energy. The Raman spectra can be explained in terms of an amorphous carbon based model, without need of extra peaks due to CN, NN or NH modes. We classify amorphous carbon nitride films in four classes, according to the corresponding N-free film: a-C:N, a-C:H:N, ta-C:...
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ژورنال
عنوان ژورنال: Nature Nanotechnology
سال: 2017
ISSN: 1748-3387,1748-3395
DOI: 10.1038/nnano.2017.226